You are on page 1of 9

SAFETY DATA SHEET

BIOC16975A

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : BIOC16975A

Other means of identification : Not applicable.

Recommended use : BIOCIDE

Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.

Company : ChampionX LLC


11177 S. Stadium Drive
Sugar Land, Texas 77478
USA
TEL: (281) 632-6500

Emergency telephone : (800) 424-9300 (24 Hours) CHEMTREC


number

Issuing date : 06/12/2020

Section: 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3
Acute toxicity (Oral) : Category 4
Acute toxicity (Inhalation) : Category 2
Skin corrosion : Category 1B
Serious eye damage : Category 1
Skin sensitization : Category 1
Reproductive toxicity : Category 2

GHS Label element


Hazard pictograms :

Signal Word : Danger

Hazard Statements : Flammable liquid and vapour.


Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Fatal if inhaled.
Suspected of damaging fertility or the unborn child.

Precautionary Statements : Prevention:


Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/ protective
clothing/ eye protection/ face protection. Wear respiratory protection.
Response:

1/9
SAFETY DATA SHEET
BIOC16975A

IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel


unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/ physician.
Storage:
Store in a well-ventilated place.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)


Quaternary ammonium compound Proprietary 10 - 30
Fatty acid-amine condensate Proprietary 5 - 10
Tetrakis(hydroxymethyl) phosphonium sulfate 55566-30-8 5 - 10
Isopropanol 67-63-0 1-5
Methanol 67-56-1 1-5
n-Alkyl dimethyl benzyl ammonium chlorides 68391-01-5 10 - 30
Tall Oil Fatty Acids, Reaction Products with Diethylenetriamine 163206-24-4 5 - 10
and Acrylic Acid
Tetrakis(hydroxymethyl) phosphonium sulfate 55566-30-8 5 - 10
Isopropanol 67-63-0 1-5
Methanol 67-56-1 1-5

Section: 4. FIRST AID MEASURES

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Section: 6. ACCIDENTAL RELEASE MEASURES

Section: 7. HANDLING AND STORAGE

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

2/9
SAFETY DATA SHEET
BIOC16975A

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible Basis


concentration
Tetrakis(hydroxymethyl) 55566-30-8 TWA 2 mg/m3 ACGIH
phosphonium sulfate
Isopropanol 67-63-0 TWA 200 ppm ACGIH
STEL 400 ppm ACGIH
TWA 400 ppm NIOSH REL
980 mg/m3
STEL 500 ppm NIOSH REL
1,225 mg/m3
TWA 400 ppm OSHA Z1
980 mg/m3
Methanol 67-56-1 TWA 200 ppm ACGIH
STEL 250 ppm ACGIH
TWA 200 ppm NIOSH REL
260 mg/m3
STEL 250 ppm NIOSH REL
325 mg/m3
TWA 200 ppm OSHA Z1
260 mg/m3

Personal protective equipment

The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based
on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk
assessment and in accordance with a PPE management program.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Colour : clear yellow
Odour : aromatic
Flash point : 54.4 °C, Method: Pensky-Martens closed cup
pH : 4.8, (20 °C)
Odour Threshold : no data available
Melting point/freezing point : -1.1 °C, ASTM D-97
Initial boiling point and boiling : 89.4 °C
range
Evaporation rate : no data available
Flammability (solid, gas) : Not applicable.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : 188.9 hPa, (37.8 °C),

3/9
SAFETY DATA SHEET
BIOC16975A

Relative vapour density : no data available


Relative density : 1.018, (20 °C),
Density : no data available
Water solubility : Miscible
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : 13.67 mPa.s (40 °C), Method: ASTM D-445
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Incompatible materials : None known.

Section: 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Experience with human exposure

Toxicity

Product
Acute oral toxicity : Acute toxicity estimate: 1,775 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: 0.25 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available

4/9
SAFETY DATA SHEET
BIOC16975A

STOT - repeated exposure : no data available


Aspiration toxicity : no data available

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components
Toxicity to fish : Isopropanol
LC50 Pimephales promelas (fathead minnow): 9,640 mg/l
Exposure time: 96 h

Methanol
LC50: 15,400 mg/l
Exposure time: 96 h

Isopropanol
LC50 Pimephales promelas (fathead minnow): 9,640 mg/l
Exposure time: 96 h

Methanol
LC50: 15,400 mg/l
Exposure time: 96 h

Components
Toxicity to daphnia and other : Quaternary ammonium compound
aquatic invertebrates EC50 : 0.47 mg/l
Exposure time: 48 h

Tetrakis(hydroxymethyl) phosphonium sulfate


LC50 : 0.16 mg/l
Exposure time: 48 h

Isopropanol
LC50 Daphnia magna (Water flea): > 10,000 mg/l

Methanol
EC50 : > 10,000 mg/l
Exposure time: 48 h

n-Alkyl dimethyl benzyl ammonium chlorides


EC50 : 0.47 mg/l
Exposure time: 48 h

Tetrakis(hydroxymethyl) phosphonium sulfate


LC50 : 0.16 mg/l
Exposure time: 48 h

Isopropanol
LC50 Daphnia magna (Water flea): > 10,000 mg/l

Methanol
EC50 : > 10,000 mg/l

5/9
SAFETY DATA SHEET
BIOC16975A

Exposure time: 48 h

Components
Toxicity to algae : Quaternary ammonium compound
NOEC : 0.009 mg/l

Tetrakis(hydroxymethyl) phosphonium sulfate


EC50 Pseudokirchneriella subcapitata (algae): 0.2 mg/l
Exposure time: 96 h

Methanol
EC50 : 22,000 mg/l
Exposure time: 72 h

n-Alkyl dimethyl benzyl ammonium chlorides


NOEC : 0.009 mg/l

Tetrakis(hydroxymethyl) phosphonium sulfate


EC50 Pseudokirchneriella subcapitata (algae): 0.2 mg/l
Exposure time: 96 h

Methanol
EC50 : 22,000 mg/l
Exposure time: 72 h

Components
Toxicity to bacteria : Isopropanol
1,050 mg/l

Methanol
> 1,000 mg/l

Isopropanol
1,050 mg/l

Methanol
> 1,000 mg/l

Components
Toxicity to fish (Chronic : Fatty acid-amine condensate
toxicity) LC50: 71 mg/l
Exposure time: 96 d

Methanol
NOEC: 7,900 mg/l
Exposure time: 8.3 d

Tall Oil Fatty Acids, Reaction Products with


Diethylenetriamine and Acrylic Acid
LC50: 71 mg/l
Exposure time: 96 d

Methanol
NOEC: 7,900 mg/l

6/9
SAFETY DATA SHEET
BIOC16975A

Exposure time: 8.3 d

Components
Toxicity to daphnia and other : Fatty acid-amine condensate
aquatic invertebrates EC50: 105 mg/l
(Chronic toxicity) Exposure time: 48 d

Tall Oil Fatty Acids, Reaction Products with


Diethylenetriamine and Acrylic Acid
EC50: 105 mg/l
Exposure time: 48 d

Persistence and degradability

no data available

Mobility

no data available

Bioaccumulative potential

no data available

Other information

no data available

Section: 13. DISPOSAL CONSIDERATIONS

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance
with the selected mode of transport.

Land transport (DOT)


Proper shipping name : CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Technical name(s) : QUATERNARY AMMONIUM COMPOUND, ISOPROPANOL
UN/ID No. : UN 2920
Transport hazard class(es) : 8, 3
Packing group : II

Air transport (IATA)


Proper shipping name : CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Technical name(s) : Quaternary ammonium compound, Isopropanol
UN/ID No. : UN 2920
Transport hazard class(es) : 8, 3
Packing group : II

Sea transport (IMDG/IMO)


Proper shipping name : CORROSIVE LIQUID, FLAMMABLE, N.O.S.

7/9
SAFETY DATA SHEET
BIOC16975A

Technical name(s) : QUATERNARY AMMONIUM COMPOUND, ISOPROPANOL


UN/ID No. : UN 2920
Transport hazard class(es) : 8, 3
Packing group : II

*Marine pollutant : Tetrakis(hydroxymethyl) phosphonium sulfate

* Note: This product is regulated as a Marine Pollutant when shipped by Rail or Highway (in bulk quantities), and
when shipped by water in all quantities.

Section: 15. REGULATORY INFORMATION

TSCA list : No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification


requirements.

EPA Reg. No. : 90924-2


EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity


This product does not contain a RQ substance, or this product contains a substance with a RQ, however the
calculated RQ exceeds the reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)


Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitisation
Reproductive toxicity

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
Methanol 67-56-1 1-5%

California Prop. 65
WARNING: Reproductive Harm - www.P65Warnings.ca.gov
Methanol 67-56-1

INTERNATIONAL CHEMICAL CONTROL LAWS :

United States TSCA Inventory


On the inventory, or in compliance with the inventory

Australia. Industrial Chemical (Notification and Assessment) Act

8/9
SAFETY DATA SHEET
BIOC16975A

On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand


not determined

Japan. ENCS - Existing and New Chemical Substances Inventory


not determined

Korea. Korean Existing Chemicals Inventory (KECI)


not determined

Philippines Inventory of Chemicals and Chemical Substances (PICCS)


On the inventory, or in compliance with the inventory

China Inventory of Existing Chemical Substances


On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory


not determined

Section: 16. OTHER INFORMATION

NFPA: HMIS III:


Flammability

HEALTH 3*
2
Instability
Health

3 0 FLAMMABILITY 2
PHYSICAL HAZARD 0

Special hazard. 0 = not significant, 1 = Slight,


2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Revision Date : 06/12/2020


Version Number : 1.2
Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.

9/9

You might also like