Patents
Patents for C07B 60 - Generation of organic free radicals (107)
05/2013
05/28/2013CA2575601C Methods for producing compositions comprising hyperpolarized 13c-pyruvate
02/2013
02/13/2013CN102924402A 1,3,2-dithiazole free-radical conjugated molecule material and preparation method and application thereof
07/2012
07/19/2012WO2012096425A1 Method for purifying high-purity methyl-4-formylbenzoate from by-products produced during preparation of dimethyl terephthalate
04/2012
04/25/2012CN102424646A 一种转化乙醇的方法 A transformed ethanol method
03/2012
03/13/2012US8134009 Process for the oxidation of secondary amines into the corresponding nitroxides
06/2011
06/22/2011CN101035796B Method of producing a composition, composition and its use
12/2010
12/02/2010US20100305322 Process for the Oxidation of Secondary Amines into the Corresponding Nitroxides
07/2009
07/22/2009CN100516007C Process for preparing stereo arrested amine nitrogen oxygen free redical with hydrotalcite analog as catalyst
11/2008
11/19/2008CN100434405C Method of generating hydroxyl free radical
09/2008
09/04/2008US20080213186 composition of Tris(8-carboxy-2,2,6,6-(tetra(methoxyethyl)benzo-[1,2-4,5']bis-(1,3)dithiole-4-yl)methyl sodium salt and hyperpolarised 13-pyruvate and pyruvic acid; radioactive C13 isotop; imaging agent for MR imaging; early stage detection of tumor
04/2008
04/24/2008US20080095713 Administering hyperpolarized C-13 pyruvate to a patient, acquiring carbon-13 magnetic resonance images of pyruvate and its metabolites alanine and lactate, correcting the lactate signal; high lactate signal indicates tumors; improved early stage detection
09/2007
09/12/2007CN101035796A Method of producing a composition, composition and its use
06/2007
06/20/2007EP1797102A1 Composition comprising triarylmethyl radical, useful in mri diagnostics
03/2007
03/20/2007CA2157147C An improved process for the preparation of n-oxyl hindered amine esters
03/07/2007CN1923769A Method of generating hydroxyl free radical
10/2006
10/24/2006US7126021 Method for preparing β-phosphorus nitroxide radicals
10/12/2006US20060229452 Process for the oxidation of secondary amines into the corresponding nitroxides
07/2006
07/26/2006EP1389175B1 Method to achieve radical gas phase reactions
06/2006
06/21/2006CN1789219A Method for initiating, capturing and measuring hydroxy radical under high temperature
03/2006
03/29/2006CN1247601C Method for preparing beta- phosphorus-contained nitroxide free radical
02/2006
02/02/2006WO2006011809A1 Method of producing a composition, composition and its use
02/02/2006CA2575601A1 Methods for producing compositions comprising hyperpolarized 13c-pyruvate
12/2005
12/21/2005EP1606259A1 Process for the oxidation of secondary amines into the corresponding nitroxides
10/2005
10/19/2005CN1683414A Process for preparing stereo arrested amine nitrogen oxygen free redical with hydrotalcite analog as catalyst
10/2004
10/07/2004WO2004085397A1 Process for the oxidation of secondary amines into the corresponding nitroxides
07/2004
07/21/2004EP1349862B1 METHOD FOR PREPARING Beta-PHOSPHOROUS NITROXIDE RADICALS
04/2004
04/22/2004US20040077873 Making beta-phosphorated nitroxide radicals by making an aminophosphonate by reaction of a carbonyl compound, of a primary amine and of a phosphorous compound in the presence of a Lewis acid and then, oxidizing using organic peracids
04/14/2004CN1489595A Method for preparing š� phosphorus-contained nitroxide free radical
02/2004
02/25/2004EP1144346B1 Method for preparing beta-phosphorous nitroxide radicals
02/18/2004EP1389175A2 Method and device to achieve radical gas phase reactions
10/2003
10/08/2003EP1349862A1 Method for preparing $g(b)-phosphorus nitroxide radicals
09/2003
09/23/2003US6624322 Method for preparing β-phosphorous nitroxide radicals
06/2003
06/04/2003EP0966414B1 Triarylmethyl free radicals as image enhancing agents
03/2003
03/06/2003WO2002094743A3 Method and device to achieve radical gas phase reactions
11/2002
11/28/2002WO2002094743A2 Method and device to achieve radical gas phase reactions
10/2002
10/03/2002WO2000040526A3 METHOD FOR PREPARING β-PHOSPHOROUS NITROXIDE RADICALS
09/2002
09/25/2002EP0839341B1 Heterogeneous photo-initiators, photopolymerisable compositions and their use
06/2002
06/26/2002CN1086686C Process for preparing stereo hindered amine nitrogen-oxygen free-radical
06/20/2002WO2002048159A1 Method for preparing $g(b)-phosphorus nitroxide radicals
05/2002
05/23/2002DE10056740A1 New polycyclic organic radicals e.g. useful in biochemistry, magnetic materials, electrically conductive materials, superconductors, analysis, oligomers and polymers
10/2001
10/17/2001EP1144346A2 Method for preparing beta-phosphorous nitroxide radicals
08/2001
08/07/2001US6271382 Reacting a cyclic secondary amine having steric hindrance with a peroxide in the presence of at least 1 part by weight of an organic compound having a cyano group
01/2001
01/10/2001EP1067120A1 Process for producing organic compound having nitroxide free radical
12/2000
12/27/2000EP0832054B1 Heterocyclic methyl free radicals as image enhancing agents
07/2000
07/13/2000WO2000040526A2 METHOD FOR PREPARING β-PHOSPHOROUS NITROXIDE RADICALS
07/06/2000WO2000039093A1 Process for producing organic compound having nitroxide free radical
05/2000
05/16/2000US6063360 Free radicals comprising benzodithiole derivatives
05/11/2000WO2000026189A1 Method for producing nitroxyl compounds of secondary amines
05/04/2000DE19850625A1 Verfahren zur Herstellung von Nitroxylverbindugen sekundärer Amine A process for preparing secondary amines Nitroxylverbindugen
04/2000
04/11/2000US6048667 Free radicals or cation polymerizable or photocrosslinkable monomers, substrates and photoinitiators, bonding with substrates
01/2000
01/11/2000US6013810 Free radicals
12/1999
12/29/1999EP0966414A1 Triarylmethyl free radicals as image enhancing agents
11/1999
11/24/1999CN1235946A Process for preparing stereo hindered amine nitrogen-oxygen free-radical
04/1999
04/29/1999DE19757851C1 Thermal gas dissociation device has an electrically conductive capillary
10/1998
10/27/1998US5827501 Use of free radicals in ESR and ESREMR imaging
09/1998
09/23/1998CN1193952A Heterocyclic methyl free radicals as image enhancing agents
09/11/1998WO1998039277A1 Triarylmethyl free radicals as image enhancing agents
08/1998
08/26/1998CN1191614A Heterogeneous photo-initiators, photopolymerisable compositions and their use
05/1998
05/06/1998EP0839341A1 Heterogeneous photo-initiators, photopolymerisable compositions and their use
04/1998
04/01/1998EP0832054A1 Heterocyclic methyl free radicals as image enhancing agents
03/1998
03/18/1998EP0662004B1 Use of persistent free-radicals in magnetic resonance imaging
03/17/1998US5728857 Silicon-containing peroxyesters
03/17/1998US5728370 Long half-life for magnetic resonance imaging
12/1997
12/23/1997US5700448 Contrast media
10/1997
10/28/1997US5681753 Solution containing a nitroxide radical for magnetometry by nuclear magnetic resonance
02/1997
02/06/1997WO1997004361A1 Heterogeneous photo-initiators, photopolymerisable compositions and their use
02/06/1997CA2227192A1 Heterogeneous photo-initiators, photopolymerisable compositions and their use
02/04/1997US5599522 Triarylmethyl radicals and the use of inert carbon free radicals in MRI
12/1996
12/12/1996WO1996039367A1 Heterocyclic methyl free radicals as image enhancing agents
12/12/1996CA2222331A1 Heterocyclic methyl free radicals as image enhancing agents
11/1996
11/12/1996US5574163 Transesterification
06/1996
06/25/1996US5530140 Triarylmethyl radicals constrast agent for magnetic resonance imaging
06/12/1996EP0716063A1 Solution containing a nitroxide radical for magnetometry by nuclear magnetic resonance
03/1996
03/27/1996EP0703220A1 Process for the preparation of N-oxyl hindered amine esters using tetraalkyl orthotitanate tranesterification catalysts
03/26/1996US5502261 Halogenation of 2,2*-dialkyl-1,1*-binaphthyl in light
03/21/1996DE4432795A1 Prepn. of 2,2,6,6-tetra:methyl piperidine-1-oxyl and derivs.
10/1995
10/04/1995EP0675095A1 Process for preparing 2,2'-bis(halogenomethyl)-1,1'-binaphthalene
09/1995
09/24/1995CA2145253A1 Process for preparing 2,2'-bis(halomethyl)-1,1'-binaphthyl
08/1995
08/23/1995EP0515458B1 Triarylmethyl radicals and the use of inert carbon free radicals in mri
07/1995
07/25/1995US5435991 Use of persistent heterocyclic free-radicals in magnetic resonance imaging
07/12/1995EP0662004A1 Use of persistent free-radicals in magnetic resonance imaging
07/11/1995US5431901 Selective isotopic labeling of spin labels for electron spin resonance spectroscopy
06/1993
06/08/1993US5218116 Catalytic peroxidation using titanium silicalite catalyst
02/1993
02/18/1993WO1993002711A1 Use of persistent free-radicals in magnetic resonance imaging
02/18/1993CA2115260A1 Use of persistent free-radicals in magnetic resonance imaging
12/1992
12/02/1992EP0515458A1 Triarylmethyl radicals and the use of inert carbon free radicals in mri.
06/1992
06/03/1992EP0488403A2 Process for the preparation of nitroxyl radicals of sterically hindered amines
08/1991
08/22/1991WO1991012024A1 Triarylmethyl radicals and the use of inert carbon free radicals in mri
08/13/1991CA2075818A1 Triarylmethyl radicals and the use of inert carbon free radicals in mri
05/1989
05/31/1989EP0147399B1 Photochemical reactions for commercial synthesis
09/1987
09/22/1987CA1227221A1 Persistent perfluoroalkyl free radicals useful as polymerization catalyst
07/1987
07/28/1987CA1224773A1 Process for obtaining free carbon radicals
05/1987
05/26/1987US4668356 Photolytic process for the formation of carbon-containing free radicals and its applications to free radical polymerization in particular
12/1986
12/02/1986US4626608 Storage stability
05/1986
05/28/1986EP0097175B1 Cartridge for injecting a semi-pasty product
01/1986
01/28/1986CA1199895A1 Cartridge for the injection of a semi-pasty product
07/1985
07/10/1985EP0147399A1 Photochemical reactions for commercial synthesis.
07/02/1985US4526295 Cartridge for injecting a semi-pasty product
06/1985
06/25/1985US4525255 Photochemical reactions for commercial synthesis
05/1985
05/15/1985EP0141690A1 Process for the formation of free carbon radicals, its applications, in particular to radical polymerization
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